The dynamic chemical diversity of the numerous elements, ions and molecules that constitute the basis of life provides wide challenges and opportunities for research. In my other articles, you can also check out more blogs about 99-55-8. COA of Formula: https://www.ambeed.com/products/99-55-8.html.
Academic researchers, R&D teams, teachers, students, policy makers and the media all rely on us to share knowledge that is reliable, accurate and cutting-edge. COA of Formula: https://www.ambeed.com/products/99-55-8.html, The appropriate choice of redox mediator can avoid electrode passivation and overpotential, which strongly inhibit the efficient activation of substrates in electrolysis. 99-55-8, Name is 2-Methyl-5-nitroaniline, SMILES is NC1=CC([N+]([O-])=O)=CC=C1C, belongs to naphthyridine compound. In a article, author is Ohtsu, Hideki, introduce new discover of the category.
The photocatalytic reduction of carbon dioxide (CO2) to value-added chemicals is an attractive strategy to utilize CO2 as a feedstock for storing renewable energy, such as solar energy, in chemical bonds. Inspired by the biological function of the nicotinamide adenine dinucleotide redox couple (NAD(+)/NADH), we have been developing transition-metal complexes containing NAD(+)/NADH-functionalized ligands to create electro-and/or photochemically renewable hydride donors for the conversion of CO2 into value-added chemicals. Our previous fi ndings have provided insights for the development of photocatalytic organic hydride reduction reactions for CO2, however, further examples, as well as investigation, of these photo-driven NAD(+)/NADH-type hydrogenation and organic hydride transfer reactions are required not only to explore the mechanism in detail but also to develop a highly ef fi cient catalyst for arti fi cial photosynthesis. In this paper, we report the synthesis, characterization, and photo-induced NAD(+)/NADH conversion properties of a new ruthenium(II) complex, [Ru(bpy)(2)(Me-pn)](PF6)(2) (1), which contains a new NAD(+)-type ligand, Me-pn (2-methyl-6-(pyridin-2-yl)-1,5-naphthyridine). In addition, we have succeeded in the isolation of the corresponding two-electron reduced ruthenium(II) complex containing the NADH-type ligand Me-pnHH (2-methyl-6-(pyridin-2-yl)-1,4-dihydro-1,5-naphthyridine), i.e., [Ru(bpy)(2)(Me-pnHH)](PF6)(2) (1HH), by the photo-induced hydrogenation reaction of 1. Thus, in this study, a new photo-driven NAD(+)/NADH-type hydrogenation reaction for possible CO2 reduction using the NAD(+)/NADH redox function has been constructed.
The dynamic chemical diversity of the numerous elements, ions and molecules that constitute the basis of life provides wide challenges and opportunities for research. In my other articles, you can also check out more blogs about 99-55-8. COA of Formula: https://www.ambeed.com/products/99-55-8.html.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem