Govindan, Venkatesan published the artcileLow-cost synthesis of heterocyclic spiro-type hole transporting materials for perovskite solar cell applications, Safety of Spiro[fluorene-9,9′-xanthene], the publication is New Journal of Chemistry (2018), 42(9), 7332-7339, database is CAplus.
Four heterocyclic spiro-type hole transporting materials (HTMs) carrying a spiro[fluorene-9,9′-xanthene] (SFX) (SFX-TPAM and SFX-TPA) or spiro[fluorene-9,9′-thioxanthene] (SFT) unit (SFT-TPAM and SFT-TPA) were synthesized through a low-cost facile route with high yields for perovskite solar cell (PSC) applications. In terms of absorption, these four compounds in the film state are all transparent at wavelengths longer than 430 nm, which is beneficial for allowing visible light to reach the perovskite active layer without being absorbed by the hole transporting layer (HTL). The photovoltaic performance of the inverted PSCs based on these small mol. HTMs with the device architecture of glass/ITO/HTL/CH3NH3PbI3/C60/BCP/Ag was tested. Only SFX-TPAM had its HOMO (HOMO) level matched with the valence band of CH3NH3PbI3. The inverted PSC based on a dopant-free SFX-TPAM HTL achieves a power conversion efficiency of 10.23% under the illumination of standard one sun lighting, which is better than that (8.17%) of the cell based on dopant-free spiro-OMeTAD. The better photovoltaic performance of SFX-TPAM compared to spiro-OMeTAD may be due to the MAPbI3 film deposited on it having better quality. These results indicate that the facilely synthesized, low-cost SFX based small mols. can be used as the HTMs for PSCs.
New Journal of Chemistry published new progress about 159-62-6. 159-62-6 belongs to naphthyridine, auxiliary class Other Aromatic Heterocyclic,Spiro, name is Spiro[fluorene-9,9′-xanthene], and the molecular formula is C25H16O, Safety of Spiro[fluorene-9,9′-xanthene].
Referemce:
https://en.wikipedia.org/wiki/1,8-Naphthyridine,
1,8-Naphthyridine | C8H6N2 – PubChem