Chemical engineers ensure the efficiency and safety of chemical processes, adapt the chemical make-up of products to meet environmental or economic needs, and apply new technologies to improve existing processes. 6165-69-1, Name is 3-Thiopheneboronic acid, molecular formula is C4H5BO2S, Recommanded Product: 6165-69-1, belongs to naphthyridine compound, is a common compound. In a patnet, author is Oyama, Dai, once mentioned the new application about 6165-69-1.
Two stereoisomers of cis-[Ru(bpy)(pynp)(CO)Cl]PF(6) (bpy = 2,2′-bipyridine, pynp 2-(2-pyridyl)-1,8-naphthyridine) were selectively prepared. The pyridyl rings of the pynp ligand in [Ru(bpy)(pynp)(CO) Cl](+) are situated trans and cis, respectively, to the CO ligand. The corresponding CH(3)CN complex ([Ru(bpy)(pynp)(CO) (CH(3)CN)](2+)) was also prepared by replacement reactions of the chlorido ligand in CH(3)CN. Using these complexes, ligand-centered redox behavior was studied by electrochemical and spectroelectrochemical techniques. The molecular structures of pynp-containing complexes (two stereoisomers of [Ru(bpy)(pynp) (CO)Cl]PF(6) and [Ru(pynp)(2)(CO)Cl]PF(6)) were determined by X-ray structure analyses. (C) 2010 Elsevier B.V. All rights reserved.
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.Welcome to check out more blogs about 6165-69-1, in my other articles. Recommanded Product: 6165-69-1.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem