Career opportunities within science and technology are seeing unprecedented growth across the world, and those who study chemistry or another natural science at university now have increasingly better career prospects. , Computed Properties of https://www.ambeed.com/products/88847-89-6.html, 88847-89-6, Name is 2-Amino-9-((2R,4S,5R)-4-hydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)-3H-purine-6,8(7H,9H)-dione, molecular formula is C10H13N5O5, belongs to naphthyridine compound. In a document, author is Chen, Chen, introduce the new discover.
Two new copper(I) complexes [Cu(L-1)(2))PF6 (L-1 = 4-diphenylphosphino-1,5-naphthyridine, 1) and]Cu(L-2)(2)] PF6 (L-2 = 4-diphenylphosphino-8-methyl-1,5-naphthyridine, 2), have been prepared and characterized. In each of them, the coordinate geometry of Cu atom is a distorted square planar configuration with bond distances and angles in the normal range. Moreover, compound 2 features one-dimensional zigzag chains which are cross-linked by the metal complex cations and PF6- anions through hydrogen bonding interactions. The HOMO-LUMO energy gaps of 1-2 estimated by the cyclic voltammetry (CV) show values in the order of 1 > 2. Both 1 and 2 show low-energy bands ranging from 360 to 430 nm and available florescence in the solid state at room temperature with lambda(max) = 532-541 nm. The UV-vis absorption spectra of 1-2 show obvious red-shifts compared with those of the corresponding quinoline containing Cu(I) complexes [Cu(QN)(2)]PF6 (QN = 8-diphenylphosphino quinoline), exhibiting the HOMO-LUMO energy gaps of 1-2 should be narrower than that of [Cu(QN)(2)]PF6. (C) 2011 Elsevier B.V. All rights reserved.
The dynamic chemical diversity of the numerous elements, ions and molecules that constitute the basis of life provides wide challenges and opportunities for research. In my other articles, you can also check out more blogs about 88847-89-6. Computed Properties of https://www.ambeed.com/products/88847-89-6.html.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem