New Advances in Chemical Research, April 2021.The transformation of simple hydrocarbons into more complex has revolutionised modern synthetic chemistry. This type of reactivity has quickly become one of the cornerstones of modern catalysis .88847-89-6, Name is 2-Amino-9-((2R,4S,5R)-4-hydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)-3H-purine-6,8(7H,9H)-dione, SMILES is O=C1N=C(N)NC2=C1NC(N2[C@@H]3O[C@H](CO)[C@@H](O)C3)=O, belongs to naphthyridine compound. In a document, author is Yao, Denghui, introduce the new discover, Name: 2-Amino-9-((2R,4S,5R)-4-hydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)-3H-purine-6,8(7H,9H)-dione.
A novel and easily synthesized compound, N-(2-(2-benzothiazol-2-yl)vinyl-4-methyl-1,8-naphthyrine-7-yl)acetamide (1) based on naphthyridine and benzothiazole group, has been developed as a turn-on fluorescent chemosensor for Al3+ and Fe3+ simultaneously. The absorbance and fluorescent intensities of 1 increased linearly in aqueous solution upon the interaction of 1 with Al3+ or Fe3+. The other co-existing metal ions have no obvious effect on the detection. The Job’s plot and the ESI mass spectra indicated the formation of 1:1 complex between 1 and Al3+ or Fe3+. The sensing mechanism was proposed according to the Job’s plot, ESI mass spectra, H-1 NMR spectra, and density functional theory (DFT) calculation. The properties of the model compound N-(2-((2-methylbenzothiazol-6-ylimino)methyl)-4-methyl-1,8-naphthyridin-7-yflacetamide (2), which was designed and synthesized in order to prove the sensing mechanism, also verified the proposed sensing mechanism. (C) 2017 Elsevier B.V. All rights reserved.
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.Welcome to check out more blogs about 88847-89-6, in my other articles. Name: 2-Amino-9-((2R,4S,5R)-4-hydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)-3H-purine-6,8(7H,9H)-dione.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem