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Synthesis and crystal structure of (1,8-naphthyridine-kappa N-2,N ‘)[2-(1H-pyrazol-1-yl)phenyl-kappa N-2(2),C-1]iridium(III) hexafluoridophosphate dichloromethane monosolvate
The solvated title salt, [Ir(C9H7N2)(2)(C8H6N2)]PF6 center dot CH2Cl2, was obtained from the reaction between 1,8-naphthyridine (NAP) and an orthometalated iridium(III) precursor containing a 1-phenylpyrazole (ppz) ligand. The asymmetric unit comprises one [Ir(ppz)(2)(NAP)](+) cation, one PF6- counter-ion and one CH2Cl2 solvent molecule. The central Ir-III atom of the [Ir(ppz)(2)(NAP)](+) cation is distorted-octahedrally coordinated by four N atoms and two C atoms, whereby two N atoms stem from the NAP ligand while the ppz ligands ligate through one N and one C atom each. In the crystal, the [Ir(ppz)(2)(NAP)](+) cations and PF6- counter-ions are connected with each other through weak intermolecular C-H center dot center dot center dot F hydrogen bonds. Together with an additional C-H center dot center dot center dot F interaction involving the solvent molecule, a three-dimensional network structure is formed.
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Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem