496-72-0, Name is 3,4-Diaminotoluene, molecular formula is C7H10N2, belongs to naphthyridines compound, is a common compound. In a patnet, author is Su, Xiao-Jun, once mentioned the new application about 496-72-0, Recommanded Product: 3,4-Diaminotoluene.
Bimetallic cooperative effect on O-O bond formation: copper polypyridyl complexes as water oxidation catalyst
The performance of water oxidation catalysis by a Cu-based polypyridyl complex, [Cu-II(TPA)(OH2)](2+) (1H; TPA = tris-(pyridylmethyl)amine), has been investigated in neutral aqueous solution by electrochemical methods. Compared with our previously reported binuclear catalyst, [(BPMAN)(Cu-II)(2)(-OH)](3+) (2; BPMAN = 2,7-[bis(2-pyridylmethyl)aminomethyl]-1,8-naphthyridine), mononuclear catalyst 1 has a higher overpotential and lower catalytic activity toward water oxidation under the same conditions. Experimental results revealed that the O-O bond formation occurred via a water nucleophilic attack mechanism in which formal Cu-IV(O) is proposed as a key intermediate for the mononuclear catalyst 1H. In contrast, for the binuclear catalyst, O-O bond formation was facilitated by bimetallic cooperation between the two Cu-III centers.
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Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem