96-49-1, Name is Ethylene carbonate, molecular formula is C3H4O3, Application In Synthesis of Ethylene carbonate, belongs to naphthyridines compound, is a common compound. In a patnet, author is Davenport, T. C., once mentioned the new application about 96-49-1.
Dinuclear first-row transition metal complexes with a naphthyridine-based dinucleating ligand
A series of dinuclear and tetranuclear first-row transition metal complexes were synthesized with the dinucleating ligand 2,7-bis(di(2-pyridyl) fluoromethyl)-1,8-naphthyridine (DPFN). The coordination pocket and rigidity of the DPFN ligand enforces pseudo-octahedral geometries about the metal centers that contain chloro, hydroxo, and aqua bridging ligands forming a diamond shaped configuration with metal-metal distances varying from 2.7826(5) to 3.2410(11) angstrom. Each metal center in the dinuclear complexes has an additional open coordination site that accommodates terminal ligands in a syn geometry of particular interest in catalyst design. The complexes are characterized by electronic spectroscopy, electrochemistry and potentiometric titration methods.
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Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem