Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 573-17-1, Name is 9-Bromophenanthrene, molecular formula is C14H9Br. In an article, author is Behlen, Michael J.,once mentioned of 573-17-1, SDS of cas: 573-17-1.
C-2-Symmetric Dinickel Catalysts for Enantioselective [4+1]-Cycloadditions
Dinickel naphthyridine-bis(oxazoline) catalysts promote enantioselective intermolecular [4 + 1]-cycloadditions of vinylidene equivalents and 1,3-dienes. The products of this reaction are methylenecyclopentenes, and the exocyclic alkene is generally obtained with high Z selectivity. E- and Z-dienes react in a stereoconvergent fashion, providing cycloadducts with the same sense of absolute stereochemistry and nearly identical ee values. This feature allows dienes that are commercially available as E/Z mixtures to be used as substrates for the cycloaddition. A DFT model for the origin of asymmetric induction is provided.
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Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem