Awesome Chemistry Experiments For 2-Chloro-1,8-naphthyridine

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Chirality control of helixes with the Delta (P) or L (M) form is interesting in various fields such as extended metal atom chains (EMACs), in which the metal backbones are helically wrapped by four ligands. Herein, we report two EMACs, Delta-[Ni5((-)camnpda)4] and Lambda -[Ni5((+)camnpda)4], whose chiralities are controlled by chiral ligands with naphthyridine and camphorsulfonyl groups. There is a large energy difference (108 kcalmo-1) between the two helical structures with one chiral ligand. Furthermore, the electron communication between [Ni2]3+ units is more pronounced than in [Ni5(bna)4Cl2]2+ (bna = binaphthyridylamido). The results demonstrate control of small-scale helical structure and set the stage for future development of chiral controlled base and nanoelectronic devices.

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Reference£º
1,494-Naphthyridine – Wikipedia,
1,8-Naphthyridine | C8H6N488 – PubChem