Olefin Oxygenation by Water on an Iridium Center was written by Ghatak, Tapas;Sarkar, Mithun;Dinda, Shrabani;Dutta, Indranil;Rahaman, S. M. Wahidur;Bera, Jitendra K.. And the article was included in Journal of the American Chemical Society in 2015.Recommanded Product: 1772625-41-8 This article mentions the following:
Oxygenation of 1,5-cyclooctadiene (COD) is achieved on an Ir center using H2O as a reagent. A H-bonding interaction with an unbound N atom of the naphthyridine-based ligand architecture promotes nucleophilic attack of H2O to the metal-bound COD. Irida-oxetane and oxo-irida-allyl compounds are isolated, products which are normally accessed from reactions with H2O2 or O2. DFT studies support a ligand-assisted H2O activation mechanism. In the experiment, the researchers used many compounds, for example, (S)-4-Benzyl-2-(1,8-naphthyridin-2-yl)-4,5-dihydrooxazole (cas: 1772625-41-8Recommanded Product: 1772625-41-8).
(S)-4-Benzyl-2-(1,8-naphthyridin-2-yl)-4,5-dihydrooxazole (cas: 1772625-41-8) belongs to naphthyridine derivatives. Heterocyclic nitrogen compounds, including fused 1,5-naphthyridines, have versatile applications in synthetic organic chemistry and play an important role in the field of medicinal chemistry, as many of them have a wide range of biological activities. Transition metal complexes of 1,5-naphthyridine (1,5-napy) seems to form one-dimensional coordination polymers with the ligand acting as bidentate in a “stepped” bridging fashion.Recommanded Product: 1772625-41-8
Referemce:
1,8-Naphthyridine – Wikipedia,
1,8-Naphthyridine | C8H6N2 – PubChem