Ghatak, Tapas’s team published research in Inorganica Chimica Acta in 372 | CAS: 14903-78-7

Inorganica Chimica Acta published new progress about 14903-78-7. 14903-78-7 belongs to naphthyridine, auxiliary class 6.6_Aromatics,Naphthyridines, name is 2,7-Dimethyl-1,8-naphthyridine, and the molecular formula is C10H10N2, Product Details of C10H10N2.

Ghatak, Tapas published the artcileA bicarbonate bridged diruthenium(I) complex: Key evidence for the decarboxylation step in the base-assisted reduction of Ru2Cl4(CO)6, Product Details of C10H10N2, the publication is Inorganica Chimica Acta (2011), 372(1), 94-99, database is CAplus.

Base-assisted reduction of [Ru(CO)3Cl2]2 in the presence of NP-Me2 (2,7-dimethyl-1,8-naphthyridine) in THF provides an unsupported diruthenium(I) complex [Ru2(CO)4Cl2(NP-Me2)2] (1). Two NP-Me2 and four carbonyls bind at equatorial positions and two chlorides occupy sites trans to the Ru-Ru single bond. Reaction of [Ru(CO)3Cl2]2, TlOTf, KOH and NP-Me2 in MeCN, in a sealed container, affords a bicarbonate bridged diruthenium(I) complex [Ru2(CO)2(μ-CO)2(μ-O2COH)(NP-Me2)2](OTf) (2). The in situ generated CO2 is the source for bicarbonate under basic reaction medium. Isolation of 2 validates the decarboxylation step in the base-assisted reduction of [RuII(CO)3Cl2]2 → [RuI2(CO)4]2+.

Inorganica Chimica Acta published new progress about 14903-78-7. 14903-78-7 belongs to naphthyridine, auxiliary class 6.6_Aromatics,Naphthyridines, name is 2,7-Dimethyl-1,8-naphthyridine, and the molecular formula is C10H10N2, Product Details of C10H10N2.

Referemce:
https://en.wikipedia.org/wiki/1,8-Naphthyridine,
1,8-Naphthyridine | C8H6N2 – PubChem