Extended knowledge of 2689-65-8

Compounds in my other articles are similar to this one(5-Iodo-2-furaldehyde)Electric Literature of C5H3IO2, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Interaction of furan derivatives with antipyrine, published in 1968, which mentions a compound: 2689-65-8, mainly applied to furyl antipyrines; antipyrines furyl, Electric Literature of C5H3IO2.

5-(R-substituted furfurals (I, R = Br or iodo) were prepared Condensation of I (R = Br or iodo) with antipyrine (II) gave diantipyryl-5-(R-substituted)furylmethanes (III, R = Br or iodo), resp. Thus, a mixture of 28.8 g. furfural in 120 ml. CH2Cl2, 0.005 g. S, and 0.05 g. hydroquinone was heated at ∼100° in a N current, 57.5 g. Br in 150 ml. CH2Cl2 added in 2 hrs., and the mixture heated 2 hrs. to give 34.3% I (R = Br), m. 81-2°. A mixture of 5.6 g. I (R = Br), 5.8 g. anhydrous KI, and 30 ml. AcOH refluxed 1.5 hrs. and kept 1 hr. gave 78.8% I (R = iodo), m. 125°. To 12.5 millimoles II in 10 ml. H2O was added 6.25 millimoles I (R = Br) in 10 ml. EtOH over in 0.5 hr. at 80-5° and the mixture worked up to give 84.2% III (R =Br). HCl salt m. 100-1° (H2O-alc.). Similarly equimol. amounts of I (R = iodo) and II gave 80% III (R = iodo). HCL salt m. 83° (EtOH).

Compounds in my other articles are similar to this one(5-Iodo-2-furaldehyde)Electric Literature of C5H3IO2, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
1,8-Naphthyridine – Wikipedia,
1,8-Naphthyridine | C8H6N2 – PubChem