The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, spectroscopic, and theoretical assessments of solvent structures and their interactions with reaction intermediates. 38002-45-8, Name is (3-Bromoprop-1-yn-1-yl)trimethylsilane, SMILES is C[Si](C)(C#CCBr)C, belongs to naphthyridine compound. In a document, author is Toche, Raghunath B., introduce the new discover, Name: (3-Bromoprop-1-yn-1-yl)trimethylsilane.
This paper describes the synthesis of 2,8-dichloroquinolin-4-amine 4 and 4,5,7-trichloro-3-(2-chloroethyl)-2-methylbenzo[h][1,6]naphthyridine 8 as novel class of building blocks. Also describes the regioselective S(N)Ar reactions of 2,4,8-trichloroquinoline 2 on C(2) and C(4) positions with azide, similarly S(N)Ar reactions of benzo[h][1,6]naphthyridine 8 at C(4), C(5) positions, and S(N)2 reactions on C(3)-(2-chloroethyl) side chain with nucleophiles such as primary aromatic amines, methoxide/ethoxide, and azide at different temperatures. (C) 2010 Elsevier Ltd. All rights reserved.
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, their interactions with reaction intermediates and transition states. I hope my blog about 38002-45-8 is helpful to your research. Name: (3-Bromoprop-1-yn-1-yl)trimethylsilane.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem