The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, spectroscopic, and theoretical assessments of solvent structures and their interactions with reaction intermediates. 1118-61-2, Name is 3-Aminocrotononitrile, SMILES is CC(N)=CC#N, belongs to naphthyridine compound. In a document, author is Sieb, David, introduce the new discover, Computed Properties of https://www.ambeed.com/products/1118-61-2.html.
Lithium indenide (Li-Ind) or cyclopentadienide (Li-Cp) derivatives react as nucleophiles with 8-(methylsulfinyl)-1,5-naphthyridine (Naph), leading to donor-functionalized ligands Ind(Naph) or Cp-Naph, respectively. The new ligands comprise two N-donor atoms, which, for geometric reasons, cannot bind to the same metal atom. In complexes, where the metal atom is bound by the Cp or Ind moiety, the N5-donor atom is located in a distal position. The coordination behavior to Rh or Zr metal centers has been investigated. The Cp-based ligands show the expected chelating coordination mode with eta(5)-Cp and N coordination, whereas the indenyl units act as dihapto, trihapto, or pentahapto ligands. The dinuclear Rh(I) complex 12 shows a rare coordination geometry with two eta(3) ligands bridging a Rh-2(CO)(3) fragment.
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Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem