Healthcare careers for chemists are once again largely based in laboratories, although increasingly there is opportunity to work at the point of care, helping with patient investigation. In an article, author is Sadhukhan, Nabanita, once mentioned the application of 298-96-4, Name is Tetrazolium Red, molecular formula is C19H15ClN4. Now introduce a scientific discovery about this category, Application In Synthesis of Tetrazolium Red.
Ferrocenylamido-naphthyridine conjugates [{(5,7-dimethyl-1,8-naphthyridin-2-yl)amino} carbonyl] ferrocene (L-1) and 1,1′-bis[{(5,7-dimethyl-1,8-naphthyridin-2-yl) amino} carbonyl] ferrocene (L-2) have been synthesized. Reaction of L-1 with [Cu(CH3CN)(6)][ClO4](2) affords [Cu(L-1)(2)][ClO4](2) (1) demonstrating tridentate coordination of the ligand utilizing naphthyridine (NP) nitrogens and carbonyl oxygen. Hydroxo-bridged neutral dirhenium(I) compound [K subset of {{Re(CO)(3)}(2)(mu-OH)(Fc(CONHNP)(CO (N) over bar NP))(2)}] (2) is reported in which the amido-NP arm of L-2 chelates a Re-I, and a K+ ion is encapsulated in a six-coordinate environment rendered by four NP nitrogens and two carbonyl oxygens involving all four arms of two L-2 ligands. Selective and reversible binding of K+ ion by the organometallic host has been recognized from electrochemical and fluorescence experiments. Partial hydrolysis of L-2 has provided a neutral metallamacrocycle [{Re(CO)(3)}(2){Fc(CO2)(CONHNP)}(2)] (3) consisting of alternate Fc and Re(CO)(3) units linked by carboxylate and amide-NP bridges. The rotational freedom of the ferrocenyl rings, the flexibility of the amide linker and the multi-site coordination of the ligands are demonstrated in the molecular structures of compounds 1-3. (C) 2009 Elsevier B. V. All rights reserved.
Therefore, this conceptually novel strategy might open impressive avenues to establish green and sustainable chemistry platforms. If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 298-96-4, Application In Synthesis of Tetrazolium Red.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem