Chemical Research Letters, May 2021. Chemistry is a science major with cience and engineering. The main research directions are chemical synthesis, and research on the structure and performance of functional materials. In an article, author is Chi, Shao-Ming, once mentioned the application of 1185-55-3, Name is Trimethoxy(methyl)silane. Now introduce a scientific discovery about this category, Safety of Trimethoxy(methyl)silane.
A new ligand napaa (napaa = 7-acetamido-4-methyl-1,8-naphthyridin-2-carbaldehyde azine) and its two dinuclear copper(I) complexes, Cu-2(napaa)(dppe)(2)(ClO4)(2) (1) and Cu-2(napaa)(PPh3)(4)(BF4)(2) (2) (dppe = 1,2-bis(diphenylphosphino)ethane) and PPh3 = triphenylphosphine) were synthesized and characterized, and the structure of 1 was determined by X-ray crystal analysis. Each copper atom in 1 has a distorted tetrahedral geometry in which the metal center is associated to napaa and dppe ligands displaying chelating coordination modes and the naphthyridine rings of napaa are almost coplanar. The two complexes exhibit similar electronic absorption spectra with lambda(max) at about 366 nm, which can be tentatively assigned to metal-to-ligand charge-transfer (MLCT) transition. The assignment was further supported by density functional theory (DFT) calculations.
The dynamic chemical diversity of the numerous elements, ions and molecules that constitute the basis of life provides wide challenges and opportunities for research. In my other articles, you can also check out more blogs about 1185-55-3. Safety of Trimethoxy(methyl)silane.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem