New Advances in Chemical Research, April 2021.The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 1185-55-3, Name is Trimethoxy(methyl)silane, SMILES is C[Si](OC)(OC)OC, belongs to naphthyridine compound. In a document, author is Chen, Yong, introduce the new discover, Category: naphthyridines.
Tetranuclear copper(I) complexes containing N,N’-bis(5,7-dimethyl-1,8-naphthyridine-2-yl)amine and phosphine ligands with close intramolecular Cu(I)center dot center dot center dot Cu(I) contacts were found to precipitate as thermodynamically stable and crystalline quasi-2D sheet-like nanostructures. Kinetically stable, amorphous, spherical particles were also identified during the precipitation/crystallization processes of these copper(I) complexes in a dichloromethane/hexane mixture. The distinct phosphorescent properties of these two forms of nanostructures were studied and a crystallization-induced emission enhancement was observed during the morphological evolution from amorphous spherical particles to crystalline nanosheets. All of these photophysical properties were rationalized by density functional theory calculations.
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.Welcome to check out more blogs about 1185-55-3, in my other articles. Category: naphthyridines.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem