New Advances in Chemical Research, April 2021.The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 23814-12-2, Name is 1H-Benzo[d][1,2,3]triazole-5-carboxylic acid, SMILES is O=C(C1=CC=C(NN=N2)C2=C1)O, belongs to naphthyridine compound. In a document, author is Fukushima, Takashi, introduce the new discover, Formula: https://www.ambeed.com/products/23814-12-2.html.
A polypyridylruthenium complex with an NAD(+)/NADH model ligand, [Ru(bpy)(2)(pbn)](2+) [bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine] in a D2O/CH3CN/triethylamine solution, undergoes stereospecific hydrogenation to give Delta-(S)- and Lambda-(R)- [Ru(bpy)(2)(pbnDD)](2+) [pbnDD = 5,10-dideutero-2-(2-pyridyl)benzo[b]-1,5-naphthyridine] upon visible-light irradiation. This result clearly indicates the pathway via the pi-stacked dimer of the deuterated one-electron-reduced species. The reduction of [Ru(bpy)(2)(pbn)](2+) with Na2S2O4 in D2O did not afford any stereospecific products. Furthermore, the more sterically crowded Ru complex, [Ru(dmb)(2)(pbn)](2+) (dmb = 6,6′-dimethyl-2,2′-bipyridine), did not produce the corresponding pbnDD species upon irradiation.
Therefore, this conceptually novel strategy might open impressive avenues to establish green and sustainable chemistry platforms. If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 23814-12-2, Formula: https://www.ambeed.com/products/23814-12-2.html.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem