New Advances in Chemical Research, April 2021. Formula: https://www.ambeed.com/products/6165-69-1.html, Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. 6165-69-1, Name is 3-Thiopheneboronic acid, SMILES is OB(C1=CSC=C1)O, belongs to naphthyridine compound. In a article, author is Oyama, Dai, introduce new discover of the category.
The asymmetric unit of the title compound, [RuCl2(C13H9N3)-(CO)(2)], consists of four crystallographically independent Ru-II complexes. Each RuII atom is in a distorted octahedral environment coordinated by two carbonyl ligands, two Cl atoms and a chelating 2-(2-pyridyl)-1,8-naphthyridine (pynp) ligand. The carbonyl ligands are cis to each other, while the Cl atoms are trans. Relatively short interatomic distances (2.60-2.67 angstrom) between the uncoordinated N atom of pynp and the C atom of the carbonyl imply a donor-acceptor interaction between the pynp and carbonyl ligands.
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Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem