Chemical Research Letters, May 2021. Chemistry is a science major with cience and engineering. The main research directions are chemical synthesis, and research on the structure and performance of functional materials. In an article, author is Gou, Gao-Zhang, once mentioned the application of 89-63-4, Name is 4-Chloro-2-nitroaniline. Now introduce a scientific discovery about this category, Name: 4-Chloro-2-nitroaniline.
Two 1,8-naphthyridine derivatives containing methylene, N-(5-methyl-7((1,3-oxo-1,3-dihydroisobenzofuran-1-yl)methyl)-1,8-naphthyridin-2-yl)acetamide (L1) and 2-amino-3((7-amino-4-methy1-1,8-naphthyridin-2-yl)methyl)isoindolin-1-one (L2), as well as a copper(I) complex CuI(L1)(2) (C1) have been synthesized through a non-catalyst C(sp(3))-H methylenation process and characterized. The structure of C1 has been determined by X-ray diffraction analysis. The spectroscopic properties have been investigated by experimental as well as theoretical studies for all these compounds. The two ligands exhibit similar electronic absorption spectra with lambda(max) at about 340 nm, which can be tentatively assigned to pi(naph)->pi(naph)* transition. The electronic absorption spectra of C1 exhibits at similar to 335 nm except in n-hexane, which may be assigned tentatively to the intraligand charge transfer transition. The assignment is further supported by density functional theory calculations and cyclic voltammetry.
The dynamic chemical diversity of the numerous elements, ions and molecules that constitute the basis of life provides wide challenges and opportunities for research. In my other articles, you can also check out more blogs about 89-63-4. Name: 4-Chloro-2-nitroaniline.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem