A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 620-92-8, Name is 4,4′-Methylenediphenol, molecular formula is C13H12O2. In an article, author is Khan, Raihana Imran,once mentioned of 620-92-8, Category: naphthyridines.
Design and one-pot synthesis of a novel pyrene based fluorescent sensor for selective turn on, naked eye detection of Ni2+ ions, and live cell imaging
A novel pyrene based fluorescent probe, 4-phenyl-2-(pyren-l-y1)-1,8-naphthyridine (Pyr-1), was designed and synthesized through tandem cyclization of pyrenealdehyde, amine and alkyne in the presence of quinolinium modified beta-CD (Qun-beta-CD) in water. Pyr-1 was characterized by H-1 NMR, C-13 NMR and ESI-MS spectra and was used as a selective turn-on and naked eye sensor for Ni2+ ion over other cations. The localized frontier molecular orbitals (DFT studies) and the solvent polarity dependent photoluminescence characteristics strongly validate the presence of photo induced electron transfer from pyrene to 1,8-naphthyridine unit in Pyr-1. Upon Ni2+ addition, the fluorescence was shifted to 450 nm due to the formation of a square planar 2:1 complex of pyr-1 with Ni2+ at room temperature even in the presence of other interfering ions such as Cd2+ and Hg2+. The resultant excimer emission and conquest of photoinduced electron transfer (PET) from pyrene moiety to the 1,8-naphthyridine part is supported by DFT studies. The sensor also exhibited very low cytotoxicity and strong fluorescence emission in living cells, indicating its potential applicability as a novel chemosensor for selective detection of Ni2+ ions in biological environment also. (C) 2018 Elsevier B.V. All rights reserved.
Interested yet? Keep reading other articles of 620-92-8, you can contact me at any time and look forward to more communication. Category: naphthyridines.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem