Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology. 40138-16-7, Name is (2-Formylphenyl)boronic acid, molecular formula is , belongs to naphthyridines compound. In a document, author is Oyama, Dai, Computed Properties of C7H7BO3.
Aqua[2-(2-pyridyl)-1,8-naphthyridine-kappa N-2(1),N-2](2,2 ‘:6 ‘,2 ”-terpyridine-kappa N-3,N ‘,N ”)ruthenium(II) bis(hexafluoridophosphate) acetone sesquisolvate
The asymmetric unit of the title compound, [Ru(C13H9N3)(C15H11N3)(H2O)](PF6)(2)center dot 1.5C(3)H(6)O, consists of two crystallographically independent RuII complexes. Each complex is approximately octahedral with the RuII atom bound by an N,N’-coordinated 2-(2-pyridyl)-1,8-naphthyridine (pynp) ligand, a meridional 2,2′:6′,2”-terpyridine (tpy) ligand and one aqua ligand. The tpy ligand is coordinated in a planar tridentate fashion with the central N atom closest to the RuII atom. The aqua ligand is trans to the pyridine N atom of pynp. The long Ru-O distances [2.150 (5) and 2.138 (5) A] are typical for aqua ligands in polypyridyl ruthenium complexes. In the crystal, both intramolecular O-H…N and intermolecular O-H…O hydrogen bonds are observed.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 40138-16-7, in my other articles. Computed Properties of C7H7BO3.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem