Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics, 136-95-8, Name is Benzo[d]thiazol-2-amine, SMILES is NC1=NC2=CC=CC=C2S1, belongs to naphthyridines compound. In a document, author is Krstic, Marjan, introduce the new discover, COA of Formula: C7H6N2S.
How to Translate the [LCu2(H)](+)-Catalysed Selective Decomposition of Formic Acid into H-2 and CO2 from the Gas Phase into a Zeolite.
Translating a homogenous catalyst into a heterogeneous catalyst requires a fundamental understanding of how the catalyst fits into the zeolite and how the reaction is influenced. Previous studies of bimetallic catalyst design identified a potent copper homobinuclear catalyst, [(L)Cu-2(H)](+) for the selective decomposition of formic acid. Here, a close interplay between theory and experiment shows how to preserve this selective reactivity within zeolites. Gas-phase experiments and DFT calculations showed that switching from 1,1-bis(diphenylphosphino)-methane ligand to the 1,8-naphthyridine ligand produced an equally potent catalyst. DFT calculations show that this new catalyst neatly fits into a zeolite which does not perturb reactivity, thus providing a unique example on how heterogenization of a homogenous catalyst for the selective catalysed extrusion of carbon dioxide from formic acid can be achieved, with important application in hydrogen storage and insitu generation of H-2.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 136-95-8 is helpful to your research. COA of Formula: C7H6N2S.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem