In an article, author is Toche, Raghunath B., once mentioned the application of 38002-45-8, Name is (3-Bromoprop-1-yn-1-yl)trimethylsilane, molecular formula is C6H11BrSi, molecular weight is 191.141, MDL number is MFCD00134460, category is naphthyridines. Now introduce a scientific discovery about this category, Category: naphthyridines.
Synthesis of novel benzo[h][1,6]naphthyridine derivatives from 4-aminoquinoline and cyclic beta-ketoester
This paper describes the synthesis of 2,8-dichloroquinolin-4-amine 4 and 4,5,7-trichloro-3-(2-chloroethyl)-2-methylbenzo[h][1,6]naphthyridine 8 as novel class of building blocks. Also describes the regioselective S(N)Ar reactions of 2,4,8-trichloroquinoline 2 on C(2) and C(4) positions with azide, similarly S(N)Ar reactions of benzo[h][1,6]naphthyridine 8 at C(4), C(5) positions, and S(N)2 reactions on C(3)-(2-chloroethyl) side chain with nucleophiles such as primary aromatic amines, methoxide/ethoxide, and azide at different temperatures. (C) 2010 Elsevier Ltd. All rights reserved.
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Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem