Chemistry is traditionally divided into organic and inorganic chemistry. category: naphthyridine, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 254-60-4
The controlled potential electrolysis of [Ru(bpy)(napy)2(CO)2](BF4)2 (1; bpy = 2,2′-bipyridine, napy = 1,8-naphthyridine) in the presence of LiBF4 in CO2-saturated DMSO at -1.65 V (vs. Ag/Ag+) produced CO and Li2CO3 [Eq. (a)], while similar electrolysis in the presence of (CH3)4NBF4 resulted in formation of acetone together with (CH3)3N and {(CH3)4N}2CO3 [Eq. (b)]. This represents the first almost selective generation of acetone upon electrochemical reduction of CO2. The selectivity is ascribed to depression of reductive cleavage of the Ru-CO bond of 1 due to an attack of the nonbonded nitrogen atom of napy at the carbonyl carbon atom.
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Reference£º
1,195-Naphthyridine – Wikipedia,
1,8-Naphthyridine | C8H6N189 – PubChem